At the moment, unless you buy from a broker, October 30 and 31 are sold out but that said, tickets may well become available nearer the time.
As for the rest, I'd say Wembley is about 30-40 minutes from central London myself and then it's about a 10 minute walk from the tube station but it's well sign-posted.
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"I want to come back as a Yorkshire Terrier, owned by me." - Stevie Nicks
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